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Bi12SiO20晶体的小面生长

Growth of Facets in Bi12SiO20 Single Crystals

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【作者】 徐学武廖晶莹沈炳孚陈显求何崇藩

【Author】 Xu Xuewu Liao Jingying Shen Bingfu Chen Xianqiu He Chongfan (Shanghai Institute of Ceramics,Academia Sinica,Shanghai,200050)

【机构】 中国科学院上海硅酸盐研究所中国科学院上海硅酸盐研究所 上海200050上海200050

【摘要】 本文用“倾倒法”获得了光折变晶体 Bi12SiO20(简称 BSO)沿<001>、<110>、<111>及<112>四种取向提拉生长的不同过程中固液界面的形态。对凸形固液界面上出现的小面(奇异面)进行了宏观观测和极图分析,确定它们是{110}和{001}面簇。计算了不同取向生长时出现各小面的凸形固液界面的曲率半径,指出<111>和<112>取向生长有利于避免小面的出现。最后,从晶体生长动力学的角度定性说明了提拉生长的 BSO 晶体形态。

【Abstract】 In this paper,the solid-liquid interface morphologies of Bi12SiO20photorefractive crystals (BSO) grown by Czochralski technique along <001>,<110>,<111>and<112> directions were obtained by abruptly withdrawingthe crystal from its melt during different growth processes.The indices ofthe facets (singular face) which appeared on the convex interfaces were de-termined to be {110} and {001} by macro-measurement and projection analysis.The curvature radii of the convex interfaces appearing the various facets werecalculated for different growth directions.It is suggested that the facets can beavoided by pulling BSO along<111> and<112> directions.Finally,the shapes ofthe grown BSO crystals were explained qualitatively on the basis of crystalgrowth kinetics.

  • 【文献出处】 人工晶体学报 ,Journal of Synthetic Crystals , 编辑部邮箱 ,1993年02期
  • 【被引频次】7
  • 【下载频次】67
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