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复吹转炉底吹不同气体时钢中氮的行为及吸氮动力学模拟研究

SIMULATION TEST FOR N2 BEHAYIOR IN BATH AND N2 ABSORPTION DYNAMICS WITH DIFFERENT BOTTOM STIRRING GAS OF COMBINED BLOWING CONVERTER

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【作者】 郭木星陈襄武

【Author】 GO Muxing Chen Xiangwu (Beijing Science and Technology University)

【机构】 北京科技大学北京科技大学

【摘要】 在感应炉上进行的底吹CO2、N2、CO2+N2的复吹模拟实验研究表明,熔池中氮的行为受底吹气体性质、脱碳速度和钢液氧化性的影响;钢液吸氮的动力学规律,随底吹气体的性质不同而有差别,底吹单一CO2或N2时,分别为二级反应和一级反应,并求得二级反应的速度常数和氮在钢液中的传质系数分别为K-1=0.044(Wt%)-1·cm·s-1,Kd=0.0308cm·s-1,底吹CO2+N2混合气体时,近似表观二级反应,其表观速度常数K2=0.0406(Wt%)-1cm·s-1

【Abstract】 A simulation test for combined blowung with bottom stirring gases of CO2、N2 and CO2+N2 in induction furnace shows that N2 behavior in the bath, will be influenced by kinds of bottom stirring gas、decarburizing rate and oxidizing property of molten steel; N2 absorption dynamics rule of the molten steel will vary with different kind of bottom stirring gases, when bottom blowing single gas: CO2 or N2, they correspond to second class and first class reaction respectively, as for second class reaction, speed constant and mass transfer coefficient of N2 in the molten steel are K-1=0. 044(wt%)-1·cm·s-1, Kd=0.0308cm·s-1; when blowing mixed gas of CO2 +N2, it approches apparent second class reaction, and its apparent speed constant is K′2=0.0406(wt%)-1·cm·s-1.

【关键词】 复吹转炉吸氮动力学
【Key words】 combined blowing converterN2 absorptiondynamics
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