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自然金-银类质同象系列矿物晶胞参数变化规律及其表述方程
THE LAW GOVERNING THE CHANGE OF AND THE EQUATION EXPRESSING THE CELL PARAMETERS OF NATIVE GOLD-SILVER ISOMORPHOUS SERIES MINERALS
【摘要】 本文提出了自然金-银类质同象系列矿物的晶胞参数与金、银原子数百分比成二次函数关系,推导出了表示二者之间函数关系的方程式。利用该方程式,可以用金原子数百分比计算出晶胞参数,反之亦然。并且从金、银二者的电负性出发,对a值的变化作了解释。
【Abstract】 The author shows clearly that in the native gold-silver isomorphous seriesthe mineral cell parameters and the atomic number of Au or Ag show a quad-ratic functional relationship. The equation expressing the functional relation-ship between them is given as follows. α=0. 00218667x~2-0. 00294667x+0. 40862 (nm)where α is the edge length of α unit cell and x is the atomic number percent-age of Au. By using the quadratic equation, the cell parameters can be calcu-lated from the atomic number percentage of Au or Ag and vice versa. On the basis of the electronegative divergence between Au and Ag, thevariation of α is explained.
【Key words】 native gold-silver isomorphous series minerals; cell parameter; atomic number of Au; electronegativity;
- 【文献出处】 矿物学报 ,Acta Mineralogica Sinica , 编辑部邮箱 ,1993年03期
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