节点文献
氯苄催化羰基化研究
CARBONYLATION OF BENZYLCHLORIDE CATALYZED BY PALLADIUM COMPLEX
【摘要】 在常温常压条件下,PdCl2(PPh3)2催化氯苄羰基化合成苯乙酸,氯苄转化率达90%~95%,苯乙酸收率达80%以上。氢氧化钠、催化剂浓度及搅拌速度对反应有较大影响。
【Abstract】 Benzyl chloride is carbonylated into phenylacetic acid by PdCl2(PPh3)2 complex at ambient condition. The conversion of ben-zylchloride is 90%-95%. The yield of phenylacetic acid is 80%. The effect of concetrations of NaOH,PdCl2(PPh3)2 and stirring speed on the reaction are also discussed in detail.
- 【文献出处】 精细化工 ,Fine Chemicals , 编辑部邮箱 ,1993年02期
- 【被引频次】11
- 【下载频次】83