【摘要】 合成了钯（Ⅱ）与五个希夫碱的七个新配合物:（L¹—H）₂Pd,（L¹—H）PdCl、（L¹）PdCl₂、（L²）PdCl₂、（L³）PdCl₂、 （L⁴）₃Pd₂Cl及（L⁵）PdCl₂,其中L¹苯甲酰丙酮缩苯甲酰肼,L²=苯甲酰丙酮缩邻苯二胺,L³=水杨醛缩苯甲酰阱,L⁴=水杨醛缩氨基脲,L⁵=双水杨醛缩邻苯二胺.用元素分析、红外光谱、紫缩外光谱、摩尔电导、热分析及荧光光谱等方法表征了它们的组成和性质,并对它们的可能结构进行了简要的讨论.更多还原

【Abstract】 Seven coordination compounds [of palladium (Ⅱ) with Sehiff bases derived by the condensation of salicylaldehyde or benzoyl acetone with a series hydrazine or diamine have been synthesized. All these complexes are characterized by elemental analyses, IR, UV-visible spectra,molar conductance, thermal analyses and fluorescence spectra. The relationship between properties and structures is disscused too.更多还原