【摘要】 通过金属铜粉和过氧化苯甲酰的氧化加成反应合成了双核铜配合物[Gu₂（OPPh₃）₂（C₆H₅CO₂）₄],以元素分析、IR,TG、磁性及粉末衍射表征了配合物的结构,并对其单晶进行了X射线衍射分析,晶体属于单斜晶系,A2/a空间群,晶胞参数为:a=2.4337（3）,b=1.0566（1）,c=2.1579（2）am;β=93.18（1）°,V=5.540（1）nm³,Z=4,F（000）=2408,D_o=1.400,D₀=1.40 g·cm^-3,μ=9.1cm^-1,最终偏离因子R=0.042,R_W0.044。更多还原

【Abstract】 Dibenzoyl peroxide undergoes oxidative addition reaction with metallic copper powder and triphenylphosphine, which affords product as a binuclear complex, [Cu₂（OPPh₃）₂（C₆H₅CO₂）4]. The structure of the complex was characterized by elemental analyses, IR, TG and X-ray powder diffraction. Crystals are monoclinic, space group A2/a, a=2.4387（3）, b=1.0556（1）, c=2.1579（2）nm, Z=4, β=93.18（1）°, V=5.540（1）nm³, R=0.042, R_w=0.044, Each copper ion is coordinated by four bridging benzoato oxygens and one triphenylphosphine oxide to form a dimeric binuclear molecule.更多还原