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(2—乙基)己基亚砜从硝酸介质中萃取裂片元素锆、铌、钌及γ辐照对萃取性质的影响

Extraction of fission products from nitric acid media by di(2-ethylhexyl) sulfoxide and influence of γ ray irradiation on its extraction properties

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【作者】 曹正白包亚之沈朝洪包伯荣王高栋钱军

【Author】 Cao Zhengbai(Sushou University, Suzhou 215006)Bao Yashi Shen Chaohong Bao Borong Wang Gaodong Qian Jun (Shanghai Institute of Nuclear Research, Academia Sinica, Shanghai 201800)

【机构】 苏州大学中国科学院上海原子核研究所中国科学院上海原子核研究所 苏州 215006上海 201800江苏工程技术翻译院上海 201800上海 201800

【摘要】 所有实验与相同条件下的TBP进行比较。结果表明(2-乙基)己基亚砜(DEHSO)萃取Zr、Nb、Ru元素的分配系数与水相硝酸浓度的变化规律和TBP相似,但DEHSO的萃取能力普遍比TBP强。在低辐照条件下,辐照对萃取分配系数几乎无影响;高辐照剂量下,辐照对这些元素萃取分配系数的影响比较复杂。DEHSO的辐解稳定性明显比TBP好。

【Abstract】 In this paper, the extraction of fission products from nitric acid media by di(2-ethylhexyl) sulfoxide(DEHSO) and the effect of γ ray irradiation on its extraction ability is described. All studies on DEHSO are compared with those on TBP. The distribution ratio of fission products as a function of aqueous nitric acid concentration is in similar manner for DEHSO and TBP,but the distribution ratio with DEHSO is usually higher than that with TBP. The radiolytic stability of DEHSO is better than that of TBP.

【基金】 国家自然科学基金
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