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气提法测定多组分混合溶剂体系的无限稀释活度系数
DETERMINATION OF INFINITE DILUTION ACTIVITY COEFFICIENTS IN MULTICOMPONENT SOLVENT SYSTEMS WITH GAS STRIPPING METHOD
【摘要】 运用加连预饱和釜技术将气提法适用范围扩展到多组分混合溶剂体系的无限稀释活度系数的测定.据此获得了298.15K温度条件下甲醇—丙酮—苯三元体系各组分的Y~∞i(j,k)值,用UNIQUAC方程关联,结果良好.
【Abstract】 The pre-saturation technique is used to extend the validity of the gas stripping method to the determination of infinite dilution activity coefficients in multicomponent solvent systems. A ternary mixture of methanol-acetone-benzene was studied at 298.15K with this method. The values measured were well correlated by the UNIQUAC equation.
【关键词】 无限稀释活度系数;
气提法;
多组分混合溶剂体系;
【Key words】 solventinfinite dilution activity coefficients; the gas stripping method; multicomponent;
【Key words】 solventinfinite dilution activity coefficients; the gas stripping method; multicomponent;
【基金】 浙江省自然科学基金资助项目
- 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,1993年05期
- 【被引频次】5
- 【下载频次】101