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二碘化钐诱导的芳族二硒醚Se—Se键还原断裂导致芳基硒负离子:β-硒代酯(腈)的制备
Samarium (Ⅱ) Diiodide—Induced Reductive Cleavage of Se—Se Bond in Diphenyl Diselenide Leading to a Samarium Phenylselenolate: Preparation of β-Phenylseleno Esters and β-Phenylseleno Nitriles
【摘要】 报导了芳族二硒醚在SmI2作用下,Se—Se键还原断裂成硒负离子。再与α,β-不饱和酯(腈)发生Michael加成反应,得到β-硒代酯(腈)。
【Abstract】 The Se-Se bond in diphenyl diselenide were reduced by Samarium (Ⅱ) diiodide to produce samarium phenylselenolate. The new selenolate anion reacted with α, β-unsaturated esters or α, β-unsaturated nitriles to give β-seleno esters and β-seleno nitrfiles, respecively.
【关键词】 二碘化钐;
二硒醚;
α,β-不饱和酯(腈);
制备;
β-硒代酯(腈);
【Key words】 Samarium diiodide; Diselenide; α; β-Unsaturated esters; β-Unsaturated nitriles; β-Selenoesters; β-Selenonitriles.;
【Key words】 Samarium diiodide; Diselenide; α; β-Unsaturated esters; β-Unsaturated nitriles; β-Selenoesters; β-Selenonitriles.;
【基金】 国家自然科学基金
- 【文献出处】 合成化学 ,Chinese Journal of Synthetic Chemistry , 编辑部邮箱 ,1993年03期
- 【被引频次】1
- 【下载频次】76