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双参数快速迭代法及其在光度分析中的应用(Ⅰ)

FAST ITERATION METHOD WITH DI-PARAMETER AND IT’S APPLICATION TO SPECTROPHOTOMETRY

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【作者】 陈桐胡勇

【Author】 Chen Tong (Department of Chemicae Engineering,Guizhou Institute of Technology)Hu Yong (Institute of the Grinding Wheel,the Seventh Grinding Wheel Factory of Guizhou,Qinzhen)

【机构】 贵州工学院化工系贵州第七砂轮厂科研所

【摘要】 本文提出双参数直接逼近法,借助计算机对一组试液进行吸光度测定,即可同时获取二元显色体系的络合物组成、显色剂用量、摩尔吸光系数以及稳定常数等多种重要信息,优于传统方法。该法应用于 Fe(Ⅱ)—邻菲罗啉显色体系,取得了令人满意的结果。文中对有关影响因素进行了初探。

【Abstract】 A simple and direct iteration method with di-parameter(G and△)is presented for simultaneous obtaining complex molar ratio, color reagent amount,molar absorptivity and stability constant in two-component coloring system by measuring absorptance of one group of solution with the aid of computer.This method is better than traditional one.And it has been successfully applied to Fe(Ⅱ)- O-phenathrolene Hydrate system.Main influential factors were also discussed.

【关键词】 迭代稳定常数分光光度法
【Key words】 iterationstability constantspectrophotometry
  • 【分类号】O657.32
  • 【下载频次】15
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