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微量稀土提高铂的高温持久强度的机理

The Mechanisms to Improve the High-Temperature Tensile Strength of Platinum with Rare Earth Elements

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【作者】 赵昆瑜黎鼎鑫

【Author】 Zhao Kunyu (Yunnan Institute of Technology, Kunming 650000) Li Dingxin (Institute of Preclous Metals, Kunming 650221)

【机构】 云南工学院贵金属研究所 昆明 650000昆明 650221

【摘要】 铂中加入双稀土元素后,其高温持久强度及蠕变断裂激活能得到很大提高。1300℃时合金的持久强度断裂时间是纯铂的23~360倍。研究表明,PtYLu合金熔炼过程中形成PtY(Lu)化合物;高温内氧化作用下形成Y2O3和Lu2O3氧化物;高温长时间作用下形成Pt2Y(Lu)化合物。大部份稀土富集在晶界上。本文对微号双稀土无素提高Pt高温持久强度的机理讲行了探讨。

【Abstract】 It has been found that the high-temperature tensile strength and creep activation energy were increased when the binary-rare earth elements had been added into platinum. At 1300℃, the time of failure of the alloys is 23~360 times longer than that of Pt. It was demonstrated that the PtY (Lu) was formed during melting, Y2O3 and Lu2O3were formed at high-temperature. The Pt2Y(Lu)was formed at high temperature and heat preservation for a long time. Most of rare earth elements were concentrated on the grain boundary of PtYLu alloy. The mechanism of the effect of rare earth elements on the platinum was discussed.

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