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尼龙-6/PP-g-MAH共混体系的结构及流变行为

THE STRUCTURE AND RHEOLOGICAL BEHAVIOR OF NYLON-6/PP-g-MAH BLENDS

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【作者】 林明德俞强芦耀南尹留芳孙载坚

【Author】 Lin Mingde, Yu Qiang, Lu Yaonan, Yin Uufang and Sun Zhaijian (Jiangsu Institute of Chemical Technology, Changzhou)

【机构】 江苏化工学院江苏化工学院 常州 213016常州 213016常州 213016

【摘要】 本文通过Molau实验、二甲苯萃取抽出物的IR分析、DSC、SEM测定了尼龙-6/PP-g-MAH的结构,发现尼龙-6与PP-g-MAH的酸酐或羧酸发生了化学反应,生成的接枝共聚物起到了共混体系增容剂的作用,改善了共混物的微观结构形态。流变学测定表明,体系假塑性增加,熔体粘度上升,共混物的成型加工性能较之纯尼龙有所改善。

【Abstract】 Utilizing Molau tests, IR analysis of the xylene extract fractions of the blends,DSC,SEM and capillary rheometer, an experimental study was conducted to investigate the structure and rheological behavior of a blend system consisting of nylon-6 and a maleic anhydride grafting PP. It was found that the graft copolymer reaulted from the reactions between nylon-6 and carboxylated PP during melt blending act as a compatibilizer, which substancially improves micro-structure morphology of blend.The theological measurements showed that compared to pure nylon, the nylon/PP-g-MAH blending system would posses higher pseudo-plasticity and melt viscosity, and better processability.

【关键词】 尼龙-6接枝马来酸酐的聚丙烯共混相溶剂流变
【Key words】 nylon-6PP-g-MAHblendingcompatibilizerrheology.
  • 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,1993年06期
  • 【被引频次】17
  • 【下载频次】124
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