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富马酸二异丙酯-富马酸二正戊酯共聚物的合成与表征
SYNTHESIS AND CHARACTERIZATION OF DI-ISO-PROPYL FUMARATE-DI-n-AMYL FUMARATE COPOLYMERS
【摘要】 本文介绍了富马酸二异丙酯(DiPF)与富马酸二正戊酯(DnAF)两种单体之间的共聚反应研究结果,得到了不同共聚组成的PDiPF/DnAF系列共聚物,并对这一系列共聚物的结构、组成进行了表征分析,研究了共聚物组成、密度及结构与其氮氧透过性的关系,还对共聚物的力学及热性能等进行了表征。
【Abstract】 Di-iso-propyl fumarate/Di-n-amyl fumarate copolymers were synthesized by means of radical polymerization. The relative reactivities of thoes DRFs monomers were determined. The structures of those copolymers were characterized by H-NMR. We have also studied the mechanical properties and the gas permeability of the copolymers.
【关键词】 反丁烯二酸二异丙酯;
反丁烯二酸二正丁酯;
共聚物;
共聚反应;
竞聚率;
【Key words】 di-iso-propyl fumarate; di-n-amyl fumarate; copolymer; copolymerization; relative reactivity.;
【Key words】 di-iso-propyl fumarate; di-n-amyl fumarate; copolymer; copolymerization; relative reactivity.;
【基金】 国家自然科学基金
- 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,1993年05期
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