节点文献
超微带电极上准稳态可逆波及其微分、半微分理论
Investigation on the Theory of Quasi-Steady-State Reversible Wave in Linear Sweep, Derivative and Semi-Differential Voltammetry at Ultramicroband Electrode
【摘要】 本文推导了超微带电极上准稳态过程可逆波及其微分、半微分伏安曲线方程式,对曲线的性质进行了详细的讨论.在K4Fe(CN)6·KCl体系中用超微金带电极对理论进行了验证,结果表明.理论与实验相符.
【Abstract】 In this paper the theory of quasi-steady-state reversible wave in linear sweep, derivative and semi-differential voltammetry at ultramicroband electrode is described. The properties of the current-potential curves are discussed. Experiments were carried out on an oscillopolarograph to verify the theory. The theoretical conclusions are in good agreement with experimental data for the oxidation of K4Fe(CN)6 in 0. 5 mol/L KCl solution at gold ultramicroband electrode.
【关键词】 线性扫描伏安法;
准稳态可逆波;
超微金带电极;
【Key words】 Linear sweep voltammetry; Quasi-steady-state reversible wave; Ultramicroband electrode;
【Key words】 Linear sweep voltammetry; Quasi-steady-state reversible wave; Ultramicroband electrode;
【基金】 国家自然科学基金
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1993年11期
- 【下载频次】39