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含偕胺肟基螯合纤维吸附、还原Au3+的研究(Ⅰ)——含偕胺肟基螯合纤维对Au3+的吸附行为
Studies on the Adsorption and Reduction of Au3+ Ion with Chelating Fiber Containing Amidoxirne Group (Ⅰ)——Adsorption Behavior of Au(Ⅱ) Ion onto Chelating Fiber Containing Amidoxime Group
【摘要】 研究了含偕胺肟基螫合纤维对Au3+的吸附特征及影响吸附量的因素。结果表明,含偕胺肟基螫合纤维对Au3+的吸附量极高,而且将所吸附的Au3+还原成单质金;在含Au3+、Cu2++、Zn2+和Cr3+的溶液中,对Au3+具有相当高的吸附选择性。提高偕胺肟基在螯合纤维中的含量及吸附温度和Au3+的初始浓度等均有利于提高吸附量。
【Abstract】 The adsorption behavior of Au(Ⅲ) ion onto the chelating fiber containing amidoxime group was investigated, and the factors to influence the adsorption capacity were discussed. The chelating fiber presents a high adsorption capacity to Au(Ⅲ) ion, and is able to reduce the adsorbed Au(Ⅲ ) ion into metallic gold. In the solution containing Au(Ⅲ),Cu(Ⅱ),Zn(Ⅱ) and Cr( Ⅲ ), the fiber presents a high selectivity to Au(Ⅲ). With increasing amidoxime group content in the fiber, temperature and initial concentration of Au(Ⅲ) ion, the adsorption rate and capacity increase.
【Key words】 Chelating fiber; Amidoxime group; Au(Ⅲ) ion. Adsorption selectivity; Metallic gold;
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1993年02期
- 【被引频次】12
- 【下载频次】201