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铟—檞皮素极谱络合吸附波测定锌盐中的痕量铟
Determination of Indium in Zinc Salt by Polarographic Adsorptive Complex Wave of Indium(Ⅲ)-Quercetin
【摘要】 在pH5的醋酸盐缓冲底液中,可获得灵敏的铟(Ⅲ)—檞皮素的络合吸附波。铟浓度由1.O×10-9—1.0×10-6mol/L与其二阶导数波峰高有正比关系,检出限为5.0×10-10mol/L,用于测定了试剂硫酸锌中的痕量铟,测得电活性络合物的组成为:In(Ⅲ):檞皮素=1:2,还讨论了络合物在汞电极上的吸附行为。
【Abstract】 In 0.lmol/L acetate buffer solution,at pH 5,a sensitive adsorptive complex wave of in (Ⅲ)-quercetin can be obtained by using single-sweep polarograpby. The detection limit is down to 5,0×1010mol/L. It was used to detetmine trace indium in zinc salt. The composition of the complex wastin=1:2.The conditonai stability constant was determined as β=6.4×108.
【基金】 国家自然科学基金
- 【文献出处】 分析科学学报 ,Journal of Analytical Science , 编辑部邮箱 ,1993年03期
- 【被引频次】6
- 【下载频次】35