【摘要】 本文阐述了一种新的光谱电化学技术——现场显微红外光谱电化学法的反射式方法的技术特点和优势,报告了一种适于水溶剂和非水溶剂的反射式现场显微红外光谱电化学池的设计,并首次在25um直径的超微铂盘工作电极上,对Fe（CN）₆^4-/FE（CN）₆^3-进行了现场显微红外光谱电化学的测量。更多还原

【Abstract】 The experimental technique of the in-situ microscopic Fourier transform infrared spectroelec-trochemistry (MFTIRS) is described. A reflectance MFTIRS cell with micro/ultramicrodisc-electrode used in both aqueous and non-aqueous solution is constructed. Well resolved optical responses of [Fe(CN)6]4+/ [Fe (CN)6]3 redox couple on a 25μm diameter Pt disc ultramicroelectrode are obtained. The versatility of this novel technique is also discussed.更多还原