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银盐分光光度法测定水和废水中的元素磷
Determination of Phosphorus in Water or Waste Water by Silver Salt Spectrophotometry
【摘要】 本文拟定一种新的分光光度法分析水或废水中的元素磷(黄磷)。水中元素磷经有机溶剂萃取后,与硝酸银溶液反应,生成亮黄色溶液,直接进行分光光度测定。检测下限0.01μg黄磷;相对标准偏差0%~8%;回收率88%~100%。方法简单、快速、选择性好、精密度和准确度高,无毒,安全。
【Abstract】 A new spectrophotometry for the determination of phosphorus (yellow phosphorus) in water or waste water is proposed. It is based on the extracted yellow phosphorus by n-heptanle and the reaction of phosphorus with nitrate silver solution to form bright yellow colour, and the determinatiom of phosphorus by spectrophotometry. The detection limit of yellow phosphorus is 0. 01μg, the relative standard deviation is 0%-8% (n = 2-4) ,the recovery is 88%-100%. The method is simple .rapid, selective, precise, accurate and harmless.
- 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1993年07期
- 【被引频次】1
- 【下载频次】64