【摘要】 研究了担载于Al₂O₃和ZrO₂上的以Ru₃（CO）₁₂为前体的[Ru]和以RuCl₃为前体的Ru催化剂的TPR特性、CO吸脱附行为及其表面加H₂反应。担载于Al₂O₃上的[Ru]和Ru催化剂上部分物相较担载于ZrO₂上者难于还原。CO在氧化[Ru]催化剂上主要以Ru（CO）yO₂表面络合物形式存在,在还原[Ru]和Ru、以及氧化Ru催化剂上CO以吸附物种形式存在。在Ru离子上的CO比在Ru原子上者难于脱附。以ZrO₂为载体的[Ru]和Ru催化剂上的CO加H₂生成CH₄的性能显著优于以Al₂O₃为载体者,担载[Ru]催化剂上的CO加H₂性能略优于担载Ru催化剂。更多还原

【Abstract】 The reduction of Ru catalysts,the adsorption-desorption and the surface hydrogenation of CO on Ru/ZrO2 and Ru/Al2O3 using Ru3(CO)12 or RuCl3 as precursor were studied.The TM values of TPR peak of the (Ru) catalyst prepared from Ru3(CO)12 and the Ru catalyst prepared from RuCl3 supported on A12O3 are higher than those of the Ru supported on ZrO2.The IR bands of CO adsorbed on the supported oxidized (Ru) catalysts are similar to the carbonyl bands corresponding to oxidized Ru surface complex,and its surface structure is mainly in the form of Ru(CO)yO2.However,the IR bands of CO adsorbed on the supported reduced (Ru) catalysts attributed to adsorbed species of various forms are essentially the same as those of the supported Ru catalysts.The chemisorption and hydrogenation centers for CO on Ru/ZrO2 and (Ru)/ ZrO2 are more than those on Ru/Al2O3 and (Ru)/Al2O3.The hydroge-nated products are composed mainly of CH4 and trace CO2.The supported (Ru) catalysts are preferable to the supported Ru catalysts in the selectivity for CH4 production.更多还原