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Na2O-CaO-TiO2-P2O5系统多孔微晶玻璃的制备

Preparation of porous glass-ceramics in Na2O-CaO-TiO2-P2O5 system

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【作者】 张志波细野秀雄阿部良弘

【Author】 Zhang Zhibo (Dalian University of Technology)Hideo Hosono and Yoshihiro Abe (Nagoya Institute of Technology, Japan)

【机构】 大连理工大学日本名古屋工业大学日本名古屋工业大学 116024

【摘要】 <正>自1934年,H·P·Hood等人发明了Vyocr glass 以来,用于制备多孔玻璃的基础玻

【Abstract】 A new type of porous glass-oeramics in Na2O-CaO-TiO2-P2O5 system has been developed by crystallization and acid leaching treatment for the base glasses. Crystalline phases were identified by X-ray diffractometer(XRD) for glass-ceramics before and after acid leaohing. The microstructure of the porous glass-ceramics was examined using scanning electron microscope (SEM). The specific surface area and the average pore radius were measured by porosimeter and BET method, respectively. The results indicate that the new porous glass-ceramics are mainly composed of crystalline CaTi4(PO4)6; The specific surface area and mean pore radius of the porous glass-ceramics were 40 m2/g and 130 A. respectively.

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