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新的维里型状态方程及其在火药燃气中的应用
A NEW VIRIAL EQUATION OF STATE AND ITS APPLICATION IN GUN PROPELLANT GAS CALCULATIONS
【摘要】 从分子运动论和分子碰撞理论出发,讨论了三分子碰撞时分子间的相互作用,提出了一种新的、简单的维里型状态方程。利用该方程计算了高压密闭爆发器中发射药燃气的压力,结果优于用其它方程计算的结果,并与实验值较为一致。
【Abstract】 Based on the kinetic theory and collision theory of molecules, molecular interactions oecuring during three-molecule collisions are discussed and a new, simplified reduced virial equation of state is proposed. With it pressures of gun propellant gases in high pressure closed-bombs have been calculated. The results are found to be better than those obtained from other forms of equations of state and agree fully with experimential data.
【关键词】 高温高压;
状态方程;
发射药;
密闭爆发器;
【Key words】 high pressure and high temperature; equation of state; gun propellant; closed-bomb;
【Key words】 high pressure and high temperature; equation of state; gun propellant; closed-bomb;
- 【文献出处】 兵工学报 ,Acta Armamentarii , 编辑部邮箱 ,1993年01期
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