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新的维里型状态方程及其在火药燃气中的应用

A NEW VIRIAL EQUATION OF STATE AND ITS APPLICATION IN GUN PROPELLANT GAS CALCULATIONS

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【作者】 於玉华曹贵桐吴杉楠渠永德

【Author】 Yu Yuhua Cao Guilong Wu Shannan (East China Institute of Technology) Qu Yongde (Xiangdong Chermical Plant, Lingyuan, Liaoning)

【机构】 华东工学院辽宁向东化工厂

【摘要】 从分子运动论和分子碰撞理论出发,讨论了三分子碰撞时分子间的相互作用,提出了一种新的、简单的维里型状态方程。利用该方程计算了高压密闭爆发器中发射药燃气的压力,结果优于用其它方程计算的结果,并与实验值较为一致。

【Abstract】 Based on the kinetic theory and collision theory of molecules, molecular interactions oecuring during three-molecule collisions are discussed and a new, simplified reduced virial equation of state is proposed. With it pressures of gun propellant gases in high pressure closed-bombs have been calculated. The results are found to be better than those obtained from other forms of equations of state and agree fully with experimential data.

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