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可移式电解槽测定涂装体系的交流阻抗

ELECTROCHEMICAL IMPEDANCE MEASUREMENTS FOR STUDYING ANTI-CORROSION COATINGS USING PROBE CELLS

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【作者】 温国谋蔡长寿刘碧环郭景东苏方腾刘仁新田伟东

【Author】 Wen Guomou, Cai Changshou, Liu Bihuan, Guo Jingdong, Su Fangteng (Fujian Institute of Research on the Structure of Matter, Academia Sinica) Liu Renxin, and Tian Weidong (The Second Automobile Factory)

【机构】 中国科学院福建物质结构研究所二部中国科学院福建物质结构研究所二部第二汽车制造厂

【摘要】 本工作采用探头式电解槽,对涂装了醇酸漆和电泳漆的A3钢片,进行了交流阻抗频谱测定,给出了评选结果,同时显示了采用双探头电解槽在评选测定应用中的优越性。

【Abstract】 The experimental approach for carrying out electrochemical impedance measuremerits for coated metals using probe cells is described. Equivalent circuit for the dualprobe cell is given, and the experimental impedance diagrams are discussed in terms ofcoating and interface properties and their changes during exposure to corrosive environmerits. The systems studied include alkyd coating and electrophoretic paints with or without inhibitor added. It is found that the potential difference △E_se for dual-probe cell taken each time before making impedance measurement has good correlation with the deterioration degree of the coating measured hereafter.

【基金】 国家自然科学基金会;中国科学院腐蚀科学开放研究实验室课题
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society for Corrosion and Protection , 编辑部邮箱 ,1992年01期
  • 【被引频次】9
  • 【下载频次】30
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