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羊红膻中新黄酮甙的分离鉴定
A New Flavone Glucoside from Thellung Pimpinella (Pimpinella thellungiana)
【摘要】 从陕西草药羊红膻Pimpinella thellungiana全草的正丁醇部分分得2个黄酮甙类化合物。经化学及光谱分析鉴定Ⅰ为洋芹素7-O-β-D-葡萄糖甙,Ⅱ为羊红膻酯(thellungianate)即洋芹素-7-O-β-D-葡萄糖酸丁酯。Ⅰ为从该植物中首次得到,Ⅱ为一新化合物。
【Abstract】 A new flavone glucoside, apigenin-7-O-β-D-glucuronide butyl ester, C15H16O11 (Ms m/z 502), mp 250~252℃ was isolated from the butanol extraction of whole plant of Pimpinella thellungiana Wolff. Its structure was established on the basis of chemical and spectroscopic analysis [UV, IR, MS (EI, FAB, FD), NMR(1H, 13C), DEPT and H-H2D-COSY].In addition, a known flavone glucoside, apigenin-7-O-β-D-glucoside was also obtained, for the first time, from same fraction of this plant.
- 【文献出处】 中草药 ,Chinese Traditional and Herbal Drugs , 编辑部邮箱 ,1992年09期
- 【分类号】R284
- 【被引频次】4
- 【下载频次】24