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额河千里光中吡咯啶型生物碱的分离鉴定及相对含量的测定
Isolation, Identification and Quantitative Determination of Pyrrolizidine Alkaloids from Argun Groundsei (Senecio argunensis)
【摘要】 从额河千里光Senecio argvnensis Turcz.中首次分得5种吡咯啶型生物碱,经MS,1H、13CNMR,GC-MS及化学方法鉴定为千里光碱(senecionine)、千里光菲灵碱(seneciphyline)和它们的氮氧化物。並通过GC-MS进一步进行了分离、纯化和相对含量的测定。另一个生物碱可能为全缘千里光碱(integerrimine),因量少未作进一步鉴定。
【Abstract】 Five pyrrolizidine alkaloids were isolated for the first time from Senecio argunensis Turcz. They were identified as senecionine, seneciphyline and N-oxides by means of spectroscopic data [1HNMR, 13CNMR (DEPT) and capillary GC-MS] and chemical methods. The remaining one, though believed to be integerrimine, was not characteriged due to lack of sufficient amount for further study.
【基金】 国家自然科学基金
- 【文献出处】 中草药 ,Chinese Traditional and Herbal Drugs , 编辑部邮箱 ,1992年06期
- 【分类号】R284
- 【被引频次】4
- 【下载频次】48