节点文献
正交试验法研制多烷基二氢化茚
Orthogonal Test in Preparation of Polyalkylindans
【摘要】 <正> 近年来,双环苯型麝香化合物对香料工业具有重要意义。如粉檀麝香、吐纳麝香等,它们具有优良的香气和与大环麝香化合物相仿的
【Abstract】 1:1,1,2,3,3, 5-Hexamethylindan is a parent constitution of polycyclic musk per-fume compounds. An orthogonal test with reaction temperature, time, amount of AlCl3 andthe molar ratio of p-cymene to 2-methyl-2-butene as factors A, B, C, D, respectively, hasbeen conducted and it is found that the optimal condition is A2B3C2D2(0℃, 3.5h, 10% and1:1.8). The products under the optimal condition have been characterized as follows: 1,1,2,3,3, 5-hexamethylindan, 36.8% and 1,1,3, 5-tetramethy1-3-ethylindan, 11.7%(relative to p-cymene).
【关键词】 大环化合物;
麝香香料(P);
粉檀麝香;
烷基茚满;
【Key words】 macrocyclic compound; polycylic musk perfume(p); phantolide; alkylindan;
【Key words】 macrocyclic compound; polycylic musk perfume(p); phantolide; alkylindan;
- 【文献出处】 有机化学 ,Chinese Journal of Organic cHEMISTRY , 编辑部邮箱 ,1992年01期
- 【被引频次】4
- 【下载频次】62