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P2S5/NH4OH处理GaAs(100)表面的电子能谱研究

ELECTRONIC SPECTROSCOPY STUDIES OF P2S5/NH4OH TREATED GaAs(100) SURFACE

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【作者】 钟战天罗文哲牟善明张开颜李侠李承芳

【Author】 ZHONG ZHAN-TIAN LUO WEN-ZHE MOU SHAN-MING ZHANG KAI-YAN LI XIA LI CHENG-FANGInstitute of Semiconductors, Academia Sinica, Beijing, 100083; National Laboratory of Surface Physics, Institute of Physics, Academia Sinica, Beijing, 100080

【机构】 中国科学院半导体研究所中国科学院半导体研究所 北京100083 中国科学院物理研究所表面物理国家重点实验室北京100080100080

【摘要】 采用俄歇电子能谱(AES)和X射线光电子能谱(XPS)研究了P2S5/NH4OH钝化液处理的GaAs(100)表面的微观特性。AES测量表明,在钝化膜和GaAs衬底之间的界面处无O组分,只有P和S组分。XPS测量分析指出,经过P2S5/NH4OH溶液处理后,GaAs表面处Ga2O3和As2O3氧化物消失了,而生成硫化镓和硫化砷。于是,降低了表面电子态密度,改善了GaAs表面的电学和光学性能。

【Abstract】 The microscopic characteristics of the GaAs(100) surface treated with P2S5/NH4OH solution has been investigated by Auger electron spectroscopy (AES) and X-ray photoemission spectroscopy(XPS). AES reveals that only phosphorus and sulfur, but no oxygen, are contain-ed in the interface between passivation film and GaAs substrate. Using XPS, it is found that both Ga2O3 and As2O3 on the GaAs surface are removed by the P2S5/NH4OH treatment, moro-ver, gallium sulfide and arsenic sulfide are formed. The passivation film results in a reduction of surfacer state density and improving both electronic and optical properties of GaAs surface.

  • 【文献出处】 物理学报 ,Acta Physica Sinica , 编辑部邮箱 ,1992年04期
  • 【被引频次】5
  • 【下载频次】31
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