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甲烷氧化偶联催化剂Li/MgO的结构及表面性质的研究

STUDY OF STRUCTURE AND SURFACE PROPERTIES OF Li/ MgO CATALYSTS FOR OXIDATIVE COUPLING OF METHANE

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【作者】 金永漱颜其洁黄庆兵王野陈懿

【Author】 JinYongshu Yan Qijie Huang Qingbing" WangYe Chen Yi (Center of Materials Analysisa and Department of Chemistry, Nanjing University, Nanjing 210008)

【机构】 南京大学现代分析中心南京大学化学系南京大学化学系 南京 210008南京 210008南京 210008

【摘要】 本文用XRD、TEM、XPS和荧光光谱等方法研究了一组不同Li+含量的Li/MgO催化剂的结构及表面性质,并与它们的氧化偶联甲烷的催化性能相关联。结果表明,低配位O2-(O3c2-)是使甲烷活化的活性中心。O1s结合能为531.9eV的氧物种是对甲烷氧化偶联反应的C2选择性起作用的活性氧物种。

【Abstract】 The structure and suface properties of Li / MgO catalysts with various Li+ content for oxidative coupling of methane have been studied using XRD, XPS, TEM andphotolumincsccnce spcctroscopy in conjunction with traditional catalytic behavior measurement. A good correlation between C2 selectivity and relative intensity of surface oxygen species corresponding to an O1s XPS peak at 531.9eV has been obtained. As an increasing amount of Li+ was added, the ratios O3c2- / O4c2- increased, passing through a maximum at 10mol% Li+ and then decreasing. The variation of the ratios with Li content paralleled the conversion of CH4, suggesting O3c2- ions are the active sites responsible for methane activation.

【基金】 国家自然科学基金
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,1992年04期
  • 【被引频次】1
  • 【下载频次】64
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