【摘要】 将二茂铁甲酰丙酮与水杨酰肼缩合,得含二茂铁基的多齿配体C₅H₅FeC₅H₄C（OH）=CHC（CH₃）=NNHCOC₆H₄OH（简记作FcacacshH₂）,该配体分别与d-过渡、ⅡB族及主族金属乙酸盐反应,合成了几个中性固体配合物。经元素分析、红外光谱、紫外—可见光谱、氢核磁共振谱、穆斯堡尔谱、摩尔电导测定对配合物进行表征并研究其性质。更多还原

【Abstract】 A new quatedentate ligand C5H5FeC5H4C(OH) = CHC(CH3) = NNHCOC6H4OH (FcacacshH2) was prepared by the condensation of ferrocenoylacetone and salicyloylhydrazine in methanol and its d-transition, H B group and main group metal complexes (FcacacshHx)yM(M = T1, x=1, y=1; M = Pb, Cd, Ni, x = 0, y=1; M = Zn, Mn, Co, x=1, y=2) were synthesized via the reaction of FcacacshH2 with relevant metal acetate. The IR, UV-Vis, 1HNMR, 57Fe Mossbauer spectra and molar conductance of the ligand and the complexes were studied.更多还原