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La1-xSrxFeO3系电子陶瓷的湿敏特性的研究

Humidity Sensitive Properties of La1-xSrxFeO3 Electronic Ceramics

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【作者】 张靖漓卢跃东吴国标李标荣

【Author】 Zhang Jingli,Lu Yuedong,Wu Guobiao and Li Biaorong (Huazhong University of Science and Technology)

【机构】 华中理工大学固体电子学系华中理工大学固体电子学系 武汉武汉武汉

【摘要】 本工作用固相反应法,合成了 La1-xSrxFeO3(0≤x≤0.7)系电子陶瓷,考察了配方对其湿敏性能的影响,用阻抗分析仪测试了材料的介电谱和复阻抗谱,用非德拜模型对其电特性进行了分析讨论,并推导了等效电路的有关参量。结果表明,La1-xSrxFeO3是一种 n 型半导瓷,LaFeO3具有负湿阻特性,而 La1-xSrxFeO3(0.1≤x≤0.4)却具有正湿阻特性,且其感湿灵敏度随 Sr 取代量的增加而增大。

【Abstract】 By using solid phase reaction method,perovskite-type La1-xSrxFe3(0≤x≤0.7)electronic ceramics were synthesized in oxygen atmosphere.Their resistance vs relativehumidity(R.H.)characteristics as well as dielectric and complex impedance spectrawere investigated.The experimental results were analyzed and discussed by non-De-bye model,and the equivalent circuit parameters were calculated.The results indi-cate that La1-xSrxFeO3 is a kind of n-type semiconducting ceramics,the resistanceof LaFeO3 decreases with the increase of R.H.,on the other hand,the resistanceof La1-xSrxFeO3(0.1≤x≤0.3)increases with the increase of R.H.,and the humi-dity sensitivity increases with the increase of x value.

【基金】 国家自然科学基金 68901003
  • 【文献出处】 无机材料学报 ,Journal of Inorganic Materials , 编辑部邮箱 ,1992年01期
  • 【被引频次】9
  • 【下载频次】85
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