【摘要】 对有机化学中的溶剂效应机理提出了新的见解,即将溶剂的配位作用分为供电子作用和受电子作用两部分,并为18种有机溶剂制定了受电子效应常数。用这一套经验参数处理4类共11种底物的红外光谱和溶剂极性参数E_T(30)的溶剂效应,均得到了预期结果。更多还原

【Abstract】 Based on the solvent effect in organic chemistry a new theory of coordination effects is suggested. The effects embody in electron pair donating and electron pair receiving. Constants of electron acception effects have been established for 18 organic solvents. With this set of empirical parameters the infrared spectra of 11 substrates of four classes were treated, and expected results were obtained.更多还原