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含氰基季铵盐杀菌剂的结构与性能

STUDY ON THE RELATIONSHIP BETWEEN THE STRUCTURE OF THE CYANOGROUP—CONTAINING QUATERNARY AMMONIUM SALTS AND THEIR BACTERICIDAL ACTIVITY

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【作者】 高宝玉乌锡康徐寿昌

【Author】 Gao Baoyu (Center of Environmental Science,Shandong Univ.,Jinan)Wu Xikang Xu Shouchang (Dept.of Environmental Eng.,East China Institute of Chemical Technology,Shanghai)

【机构】 山东大学环境科学中心华东化工学院环境工程系华东化工学院环境工程系

【摘要】 合成了4种含氰基季铵盐,比较了它们的杀菌活性;探讨了12种含氰基季铵盐的结构与杀菌性能之间的关系;试验了污水含油量、pH 值、温度对杀菌效果的影响及杀菌剂的贮存稳定性。结果表明:含氰基季铵盐的杀菌活性与其分子结构密切相关,分子的结构对称性越高,其杀菌活性越低;在杀菌剂浓度一定的情况下,杀菌剂的杀菌活性随污水含油量的增加而下降;含氰基季铵盐具有良好的贮存稳定性,在偏碱性及温度较高的条件下具有较好的杀菌效果。

【Abstract】 Four kinds of cyanogroup-containing quaternary ammonium salts have been prepared.The relationship between the structure of twelve kinds of cyanogroup-containing quaternaryammonium salts and their bactericidal activity has been discussed.The factors influencing thebactericidal activity of these cyanogroup-containing quaternary ammonium salts,includingthe oil content in waste water,the pH value,the temperature and the storage period of watersolution of these cyanogroup-containing quaternary ammonium salts,are studied experimen-tally.The experimental results show that the bactericidal activity of these cyanogroup-con-taining quaternary ammonium salts has close relation with their molecular structure,themore symmetrical the structure of these cyanogroup-containing quaternary ammonium saltsis,the less their bactericidal activity is;With the increase of oil content in waste water,thebactericidal activity of these cyanogroup-containing quaternary ammonium salts decreases;The cyanogroup-containing quaternary ammonium salts have long storage life and give com-paratively good results in bactericidal activity in weakly basic solution and in solution withslighly high temperature.

  • 【文献出处】 山东大学学报(自然科学版) ,Journal of Shandong University , 编辑部邮箱 ,1992年04期
  • 【被引频次】3
  • 【下载频次】68
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