节点文献
苯甲酰氯亲核取代反应的热动力学研究
STUDY ON THE THERMOKINETICS FOR NUCLEOPHILIC SUBSTITUTION REACTIONS OF BENZOYL CHLORIDE
【摘要】 研究了苯甲酰氯水解和胺解两个反应体系的热动力学,求得了反应的速度常数、活化能和活化熵,讨论了取代基对化学反应速度的影响和反应机理.
【Abstract】 The hydrolysis and ammonolysis of benzoyl chloride have been studied by the method of dimensionless parameter. The rate constants and the activation energies and the activation entrpies for these reactions have been found. The influence of substituents on the reaction rates and the mechanisms of these reactions have been discussed.
【基金】 国家自然科学基金资助项目
- 【文献出处】 四川大学学报(自然科学版) ,Journal of Sichuan University (Natural Science Edition) , 编辑部邮箱 ,1992年04期
- 【被引频次】3
- 【下载频次】319