【摘要】 用EMF方法测定了实际转炉吹炼过程的冰铜、白冰铜和粗铜试样中S和Fe的活度。S活度的测定采用β-Al₂O₃固体电解质和含有Na₂S的熔渣构成电池 W,WS₂,(Na⁺,S^2-)|β-Al₂O₃|(Na⁺,S^2-),[Cu-Fe-S],W Fe活度的测定采用Zr02（CaO）固体电解质和含有FeO的熔渣构成电池 Fe,(Fe²⁺,O^2-)|ZrO₂（CaO）|(Fe²⁺,O^2-),[Cu-Fe-S],W 实验结果显示了实际冰铜熔体在转炉吹炼过程中S和Fe活度变化情况的一般特征。更多还原

【Abstract】 Activities of S and Fe in melts of matte, white metal and blister Cu were determined by the cells, respectively, as: W, WS₂, (Na⁺, S^2-) |β-3-Al₂O₃| (Na⁺, S^2-), [Cu-Fe-S],W and Fe, (Fe²⁺, O^2-) |ZrO₂（CaO）| (Fe²⁺, O^2-), [Cu-Fe-S],W The activities of S and Fe were measured to decrease gradually from 0.22 to 6.0×10^-5 and from 0.51 to 0.010, respectively, at 1473 K during matte converting process.更多还原