【摘要】 用改进的Aider方法合成了四(对-硝基)苯基卟啉Cr(Ⅲ),Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)配合物。用元素分析、紫外可见光谱、红外光谱、激光拉曼光谱、X射线光电子能谱等方法表征了配合物的组成和结构。用紫外可见光谱和红外差谱研究了一氧化氮配合物的光谱性质。更多还原

【Abstract】 The improved Adler’s method was used to prepare the complexes of tetra-(p-nitro-phenyl) porphyrinatometal. The structures and compositions of the complexes were determined by elemental ananlysis, UV, IR, Raman and XPS. Adducts of the complexes with nitric oxide were studied by UV-VIS spectra and infrared subtracted spectra.更多还原