【摘要】 本文讨论了复杂反应系统中实际最大产率与综合平衡产率之间的关系。由于相邻简单反应之间存在着热力学竞争与动力学竞争,在适当条件下一种产物的实际最大产率有可能超过其综合平衡产率。文中提出了实际最大产率超过综合平衡产率的条件判别式,引入了判别因子。可根据判别因子及其它有关参数估计实际最大产率,并可对复杂反应系统的反应现象作出适当的解释。更多还原

【Abstract】 The reaction between Actual Maximum Yield (AMY) and Global Equilibrium Yield(GEY) in complex reaction systems are discussed. Because of thermodynamic and kinetic competitions among neighboring single reactions, AMY may be beyond the limits of GEY under certain conditions. A discriminant for the condition of AMY beyond GEY and discrimination factor are presented in this paper. According to the factor and other relative parameter, AMY can be estimated, and reaction phenomena in complex reaction systems can be explained.更多还原