节点文献
交流示波极谱法中i_f-E曲线的研究——Ⅷ.“电极/溶液”界面动态双电层微分电容的快速测量
Investigations on i_f-E Curve in Cyclic Derivative Chronopotentiometry Ⅷ. Measurement of the Dynamic Double-layer Oapacitence
【摘要】 “电极/溶液”界面动态双电层微分电容是电极过程动力学中一个重要的物理量.但其测量方法.多数仍停留在对逐一测定的数据点进行作图分析上.本文以i(?)-E曲线上电流峰的理论公式为基础,提出了一个快速测量“电极/溶液”界面动态双电层微分电容的新方法.
【Abstract】 Several methods for measuring the dynamic double-layer capacitance, i.e. the double-layer capacitance in the presence of faradaic process have been reported, but most of them require a graphical analysis of individually obtained data points. Because the importanoe of the dynamic double-layer capacitance in electrode kinetics, a new method for measuring the dynamic double-layer capacitance automatically has been proposed on the basis of the fundamental equations of i_f-E curve.
【基金】 国家自然科学基金资助课题
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,1992年07期
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