【摘要】 本文报道了2,6-吡啶二甲酸（dipcH₂）合钴配合物:[dipo Co（μ-4,4′-bpy）Co dipc]·8H₂O（1）,[dipc Co（ImH）₂]_n（2）的合成和它们的晶体结构。配合物1:单斜晶系。空间群为P2₁/c。a=1.0614（5）,b=2.0144（8）,c=0.7342（2）nm;β=106.33（3）°;Z=2。最后的偏正因子R₁=0.043。由4,4′-bpy桥联形成双核Co配合物。4,4′-bpy中两个吡啶环共平面。配合物2:正交晶系。空间群为P2₁2₁2₁,a=0.9011（5）nm,b=1.0078（1）nm,c=1.6625（2）nm;Z=4。最后的偏正因子R₁=0.033。dipc中羧氧原子参与了和另一Co（Ⅱ）配位,形成链状结构。两个ImH处于反位,二面角为44.4°。更多还原

【Abstract】 Synthesis and crystal structure of pyridine-2, 6-dicarboxylate complexes, [（dipc） Co（μ-4, 4’-bpy）Co（dipc）]·8H₂O（1）, [（dipc）Co（ImH）₂]_n（2）, were reported in this paper. Complex 1: monodinic, space group P2₁/c with a=1.0614（5）, b=2.0144（8）, c=0.7342（2）nm, β=106.33（3）°, Z=2, final R₁=0.043. The binuclear cobalt complex is formed with 4, 4’-bpy as a bridging ligand. The two pyridine ring of the 4, 4’-bpy are coplane in the complex. Complex 2: orthorhombic, space group P 2₁2₁2₁ with a=0.9011（5）, b=1.0078（1）, c=1.6625（2）nm, Z=4, final R₁=0.033. One of O—C—O of dipc is coordinated to another Co（Ⅱ）, forming a chain structure. Two Im H ligands are located at axial positions with dihedralangle 44.4°.更多还原