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Cadion AP的合成及其与金属离子的显色反应
Synthesis of antipyrinyldiazoaminoazobenzene and study on its colour reaction with some metal ions
【摘要】 介绍了氨替比林基重氮氨基偶氮苯的合成方法。用光度法测定的它在 Triton X-100存在下的二级离解常数分别为(6.0±0.3)×10-2,(5.9±0.4)×10-12。在 pH11.5时,与镉和汞的配合物的表观摩尔吸光系数分别是2.11×105L·mol-5·cm-1和1.61×105L·mol-1·cm-1。
【Abstract】 This paper described the method of synthesisof antipyrinyldiazoaminoazobenzene(Cadion AP).Its dissociation constants were determined byspectrophotometry in the presence of Triton X-100.They are K-(a1)=(6.0±0.3)x10-2and Ka2=(5.9±0.4)×10-12respectively.The colour reac-tion of Cadion AP with metal ions was studiedat pH 11.5 and in the presence of Triton X-100,the apparent molar absorptivities of complexesfor Cd(Ⅱ),Hg(Ⅱ)are 2.11×105 and 1.61×105L.mol-1·cm-1respectively.
- 【文献出处】 化学试剂 ,Chemical Reagents , 编辑部邮箱 ,1992年04期
- 【被引频次】23
- 【下载频次】31