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硼对YBa2Cu3O7-δ陶瓷超导体超导性质的影响
THE INFLUENCE OF BORON ON SUPERCONDUCTING PROPERTIES OF YBa2Cu3O7-δ CERAMIC SUPERCONDUCTORS
【摘要】 制成组分为0≤x≤0.1的超导材料Y1-xBxBa2Cu3Oy.测量了从液氮温度到室温的该材料的电阻、磁化率和比热,并在室温下用X射线粉末衍射法分析了样品.结果表明掺硼减少了超导相的构成,引起部分非超导相.在硼浓度低时,没有迹象表明硼阳离子进入铜-氧面或铜-氧链.
【Abstract】 Superconducting materials Y1-xBxBa2Cu3Oy, with 0≤x≤0.1 have been made.The resistance, susceptibility and specific heat of these materials have been measured fromliquid nitrogen to room temperature and the samples analyzed with X-ray powder diffrac-tion at room temperature. The results indicate that the doping of boron reduces the forma-tion of superconducting phase and induces a part of nonsuperconducting phase. There is noevidence that the cation of boron goes to the copper-oxygen planes or chains in the case oflow concentrations of boron.
【关键词】 硼;
YBaCuO超导体;
X射线衍射法;
超导相;
非超导相;
【Key words】 boron; YBaCuO superconductors; X-ray diffraction; superconducting phase; nonsuperconducting phase;
【Key words】 boron; YBaCuO superconductors; X-ray diffraction; superconducting phase; nonsuperconducting phase;
- 【文献出处】 红外与毫米波学报 ,Journal Infrared Millimeter and Waves , 编辑部邮箱 ,1992年02期
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