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镧-溴邻苯三酚红-亚甲蓝配合物的紫外可见光谱研究
The UV-VIS Spectra Study on Coordination Compound of Lanthanum with Bromopyrogallol Red and Methylene Blue
【摘要】 本文研究了镧的溴邻苯三酚红配离子与亚甲蓝形成沉淀的最佳条件,测定了沉淀的组成和溶度积,研究了该三元离子对体系的吸光性质,可作为沉淀、分离、高灵敏协同显色反应测定微量镧的新方法。
【Abstract】 Lanthanum ion reacts with bromopyrogallol red at oplimurn pH5.5~ 6.0 to give a blue complex which reacts with methylene blue to give an isochromatic ion-pair complex. The association capability and the absorption properties of the ion-pair system were studied Owing to the isochromatic effect of the ion-pairs, the sensitivity for the dctermination of lanthanum is enhanced .It can be used as a new method in the determination of lanthanum (Ⅲ)
- 【文献出处】 河北大学学报(自然科学版) ,Journal of Hebei University(Natural Science Edition) , 编辑部邮箱 ,1992年03期
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