节点文献
烷基取代酮羰基n→π~*跃迁的光谱规律
THE n→π~* TRANSITION RULE OF ALKYL SUBSTITUTED KETONES
【摘要】 本文提出了开链酮化合物n→π跃迁的λmax与酮羰基α-,β-位碳上烷基取代关系的经验公式。
【Abstract】 There is a correlation between the carboxyl n→π* transition band of the α-,β-methyl substituted ketones and the quantity of the substituting group. The authors have derived the following equation: λN=λ0(N+α)/αm or λN=λ0+λ′Nn The data calculated from the equation are completely consistent with the experimental values.
- 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,1992年05期
- 【被引频次】1
- 【下载频次】43