【摘要】 用红外透射光谱法,在295～368K范围内,作CO在AgY分子筛上的等温吸附线,建立CO在Ag_n~+原子簇上的等量吸附热,其值为35.6kJ/mol,对应吸附熵值为0.163kJ/mol·K,从而获得了Co与Ag_n~+的吸附键能量为42.20kJ/mol。更多还原

【Abstract】 The isothermo adsorption curves for carbon monoxide adsorption on Ag_n⁺ ions. of AgY zeolite were carried out on the in-situ IR spectrum system at 2178cm^-1, 295～368K temperature range. The isosteric heat of adsorption was calculated on the basis of In P versus 1/T curve at each amount adsorbed. The results show that the isosteric heat and entropy of adsorption only depended to a minor degree upon amount adsorbed over the experiment all range （200～2133Pa）. Because of this behavious the values of isosteric heat and entropy of adsorption are near 35.60 kJ/mol and 0.163 kJ/mol-K respectively, subsequently, the bond energy of adsorption, Ag_n⁺—Co, is 42.20kJ/mol.更多还原