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化学偶联反应条件探析
Investigation into Conditions of Chemical Coupled Reaction
【摘要】 本文对化学偶联反应的发生条件加以详细探析,发现化学偶联反应的发生不仅需满足已知的特定热力学条件,而且也应满足一定的动力学条件.若只有两个基元反应偶联,在弛豫时间里,该动力学条件:JT1A12—JT2A22>0,这一结果也说明了文献[3]中的结论存在一定的片面性.
【Abstract】 In this paper are investigated conditions of chemical coupledreactions, and is discovered that not only some known thermodynamicsconditions, but also a dynamics condition must be satisfied. To twoelementary reactions coupling, the dynamics condition is A12Jr1 -A22Jr2>0, This result shows that Li’ s result did not seem suitable.
- 【文献出处】 齐齐哈尔师范学院学报(自然科学版) , 编辑部邮箱 ,1992年03期
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