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中性载体ETH157推动Cu²⁺离子在水/硝基苯界面上的转移

Cupric Ion Transfer Across the Water/Nitrobenzene Interface Facilitated by lonophore ETH157

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【Author】 QI De-Yao,XU Cheng-Min (Department of Chemistry and Chemical Engineering,Shanghai University of Technology,Shanghai,200072)YU Ze-Mu,WANG Er-Kang(Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,130022)

【机构】上海工业大学化学化工系；中国科学院长春应用化学研究所电分析化学开放研究实验室；中国科学院长春应用化学研究所电分析化学开放研究实验室上海200072；上海200072；长春130022；长春130022；

【摘要】本文用循环伏安法研究了中性载体ETH157推动Cu²⁺离子在水/硝基苯界面上的转移过程,结果发现在水/硝基苯界面上,Cu²⁺离子与ETH157形成了逐级配合物,并伴有吸附现象产生,考察了有关过程的转移机制并讨论了相应的实验现象。更多还原

【Abstract】 The transfer process of cupric ion across the water/nitrobenzene interface facilitated by ETH157 has been studied by cyclic voltammetry.It has been concluded that the successive complex-formation between Cu2+ ion and ETH157 has occurred and coupled with adsorption phenomenon at the water/nitrobenzene interface.The mechanism of the transfer process is discussed.更多还原