【摘要】 本文首次制得了二价稀土与含硫有机配体的固态配合物RE(SSCNC₁₃H₁₁NO)₂·xH₂O（RE=Sm,Eu,Yb,x=3,4）,研究了它们的性质,并对二价及相应的三价稀土配合物在物理化学性质上的差异进行了探讨。更多还原

【Abstract】 The new solid complexes of divalent rare earth with 3-phenyl-5-(furyl-2)pyrazoline dithioformate RE(SSCNC13HuNO)2.xH2O(RE= Sm, Eu, Yb, x=3,4) were prepared in Ar atmosphere. The composition and properties of the complexes as well as the differences between di- and trivalent rare earth complexes were studied on the basis of elemental analyses, IR spectra, electron spin resonance spectra, thermogravimetry, differential thermal analyses and the test for reducing property of the divalent rare earth complexes.更多还原