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铜(Ⅱ)-铬天青S-过氧化氢体系催化光度法测定痕量铜

Study on Catalytic Spectrophotometric Determination of Trace Copper with the System of Copper-Chrome Azurol S-Hydrogen Peroxide

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【作者】 董存智董彦訾言勤

【Author】 Dong Cunzhi, Dong Yah and Zi Yanqin (Department of Chemistry, Huaibei Coal Teachers College, Huaibei 235000)

【机构】 淮北煤炭师范学院化学系淮北煤炭师范学院化学系 淮北 235000淮北 235000淮北 235000

【摘要】 本文研究了在氨水介质中,痕量铜对过氧化氢氧化铬天青S褪色反应的催化作用,建立了一个催化光度法测定痕量铜的新方法。线性范围为0~20ng/mL,检出限为5.59×10-11g/mL,并用于铝合金标准样品,环境标准样品和自来水中痕量铜的测定。

【Abstract】 Based on the fact that trace copper catalyzes the color-fading oxidation reaction of chrome azurol S by hydrogen peroxide in a medium of ammonia water, a new method for catalytic spectrophotometric determination of trace copper has been developed. The linear range is 0~20ng/mL and the limit of detection is 5.59×10-11g/mL. It has been used to determine trace copper in standard sample of aluminium alloys, standard sample of environment and tapwater.

  • 【文献出处】 分析试验室 ,Analytical Laboratory , 编辑部邮箱 ,1992年05期
  • 【被引频次】10
  • 【下载频次】39
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