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大孔β-二酮螯合树脂的合成及其对铍(Ⅱ)的吸附特性

Synthesis of Macroporous β-Diketone Resins and Their Chelating Property for Beryllium

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【作者】 刘道杰刘奉辉柳仁民

【Author】 Liu Daojie~*, Liu Fenghui, Liu Renmin(Department of Chemistry, Liaocheng Teachers’ College, Liaocheng 252059)

【机构】 聊城师范学院化学系聊城师范学院化学系 聊城 252059聊城 252059聊城 252059

【摘要】 首次报道了用双乙烯酮与氨基聚苯乙烯缩合制得N-乙酰乙酰苯胺基螯合树脂的方法。试验树脂对十几种金属离子的螯合性能,结果表明,pH=4.0时树脂对Be2+有良好的吸附选择性,其吸附容量为0.43m mol/g干树脂。用6mol/L H2SO4可从树脂柱上定量洗脱出Be2+

【Abstract】 A method for the preparation of chelating resin containing acetoacetanilide group was reported based on the condensation reaction of diketo with aminopolystyrene in toluene at atmospheric temperature, The resin is stable in fairly strong acid or alkaline solution. The sorption patterns of several metal ions have been studied at varying pH. The results showed that the resin has a good selectivity to Be((2+) at pH 4.0. The adsorption capacity was 0.43m mol/g-resin. The Be2+sorbed on the resin column can be quan- titatively eluted with 6mol/L H2SO4,

【关键词】 螯合树脂N-乙酰基乙酰苯胺
【Key words】 Chelating resinAcetoacetanilideBeryllium
  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1992年11期
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