节点文献
一种超高灵敏测定铁(Ⅲ)分析方法的研究
Highly Sensitive Determination of Iron(Ⅲ)
【摘要】 在稀盐酸介质中,在锰(Ⅱ)存在下,沸水浴中加热,铁(Ⅲ)迅速氧化二安替比林苯乙烯甲烷形成一种红色化合物。该化合物最大吸收峰位于波长540nm,摩尔吸光系数为1.44×106L·mol-1·cm-1。铁(Ⅲ)浓度在0.04~0.8μg/25ml范围符合比耳定律。方法曾用于天然水中痕量铁(Ⅲ)的测定,结果令人满意。
【Abstract】 In the presence of dilute hydrochloric acid and Mn(Ⅱ), Fe(Ⅲ)reacts with diantipyrylphenyl ethylenemethane to form a red compound in 100℃ water baths its mclar, absorptivity is 1.44×106 L.mol-1. cm-1 at 540nm. Eeer’s law is obeyed in the range of 0.04~0.8μg Fe(Ⅲ)/25ml. The method has been applied to the determination of trace Fe(Ⅲ)in natural water With reliable results.
【关键词】 铁;
分光光度法;
超高灵敏显色反应;
二安替比林苯乙烯甲烷;
【Key words】 Iron; Spectrophotometry; Colour reaction; Diantipyrylphenyl ethylenemethane.;
【Key words】 Iron; Spectrophotometry; Colour reaction; Diantipyrylphenyl ethylenemethane.;
- 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1992年08期
- 【被引频次】1
- 【下载频次】32