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高精度热电离质谱法测定铟同位素
Measurement of Indium Isotope by High-precision Thermal Ionization Mass Spectrometry
【摘要】 本文系统研究了高精度热电离质谱测定铟同位素的方法,采用磷酸涂样技术,获得了强而稳定的In+离子流,5种锢试剂中的平均113In/115In比值为0.044804±0.000055(2SD),由此比值计算的铟原子量为114.8185(2)比现行的114.82更为精密。
【Abstract】 A method for the measurement of indium isotope in chemical reagents by high precision thermal ionization mass spectrometry has been studied. The strong and stable In+ ion beam was obtained by using the technique of loading sample with H3PO4.The average ratio of 113In/115In for five indium reagents was 0.044804 with the precision of 0.05%, andthe calculated atomic weight of indium was 114.8185 which is more precise than 114.82 listed on the periodic table of the elements.
- 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1992年04期
- 【被引频次】4
- 【下载频次】47