【摘要】 测定了化学修饰[NiFe（CN）₆]^2-/1-电极在NaBr或KBr（以NaNO₃或KNO₃为支持电解质）溶液中的循环伏安图,发现该电极对Br^-的电化学氧化有明显的电催化作用,并对其催化机理进行了讨论。研究结果表明,在D+—葡萄糖电化学氧化制备D₊—葡萄糖酸盐方面,[NiFe（CN）₆]^2-/1-电极是一种优越的电极材料,在反应过程中NaBr起催化剂的作用。更多还原

【Abstract】 in this paper authors reported that the cyclic voltammograms of the nickel ferrocyanide film electrode in NaBr or KBr solution （the supporting electrolyte is NaNO₃ or KNO₃）. It had been found that the nickel ferrocyanide film had obviously part in electrochemical catalyzed oxidation of Br-. The catalyzed mechanism was discussed. The NaBr played a role in action of catalyst in D₊-glucose electrooxidatingto product glyconate. The experiment result showed that nickel ferrocyanide film electrode is a favourable electrode on producting glyconate from D₊-glucose by method of the electrochemical oxidation.更多还原